A small, crusted meteorite found in Algeria in November 2004 joins NWA 1195, NWA 2046 and DaG 476 as olivine-orthopyroxene-phyric shergottites, which represent the most primitive igneous rocks known from Mars, and may be samples from the young Tharsis volcanoes. This latest 31.07 gram stone, purchased in Morocco by Mike Farmer and Jim Strope, was studied by Drs. Ted Bunch and Tony Irving and their colleagues Drs. James Wittke and Scott Kuehner at Northern Arizona University and the University of Washington in Seattle. Like NWA 2046, this specimen contains relatively large crystals of both olivine and orthopyroxene which exhibit a preferred alignment as a result of magmatic flow processes. The finer grained groundmass of the rock consists of compositionally-zoned clinopyroxene (pigeonite and some augite), maskelynitized plagioclase, smaller olivine grains, titanium-rich chromite, chromite, merrillite, ilmenite, ulvöspinel and pyrrhotite. Although this sample is similar to NWA 1195 and NWA 2046, it differs from them in having much less extensive compositional zoning in pyroxene and olivine. Other distinctive features are irregular patches of late-crystallizing merrillite adjacent to groundmass pigeonite grains and within maskelynite grains, and moat-like cavities around maskelynite grains (which formerly may have contained soluble salts or soft alteration assemblages of Martian origin). NWA 2626 is further distinguished by the presence of cross-cutting veinlets and small pockets of dark glass with quenched crystallites, which are interpreted to have formed by shock-induced melting as this specimen was ejected from Mars.
Speculation that NWA 2626 and most of the other olivine-phyric to basaltic shergottites are samples of volcanic and subvolcanic rocks from the large Tharsis volcanoes is based mainly on the relatively young crystallization ages for shergottites (575-165 million years) coupled with the evidence from Mars Global Surveyor and Mars Express imagery for very young volcanism on Olympus Mons and Arsia Mons. Very few other candidate sites on Mars are as likely to have had the sustained and intermittently replenished magmatic systems capable of fractional crystallization, mixing and flow processes reflected in the textures and compositional range of the shergottites, and furthermore these immense volcanic edifices may have greater potential for efficient ejection of rock fragments by low-angle impacts.
Northwest Africa 2626 Algeria Purchased 2004 November Martian meteorite (basaltic shergottite) A 31.07 g completely crusted stone found at an unknown site in Algeria was purchased from a Moroccan dealer in 2004 November by M. Farmer (Farmer). The ellipsoidal stone measured 28.9 mm by 16 mm by ~ 15 mm, and has a 1 to 2 mm thick weathering rind; the dark greenish interior is very fresh and unweathered, but contains thin, glass-rich veinlets and pockets, presumably produced by shock. Classification and mineralogy (A. Irving and S. Kuehner, UWS; J. Wittke and T. Bunch, NAU): olivine-orthopyroxene-phyric basaltic rock composed of euhedral to subhedral olivine phenocrysts and preferentially-oriented, prismatic low-Ca pyroxene phenocrysts in a groundmass of zoned pigeonite (Fs26.4Wo12.4 to Fs34.1Wo12.4), maskelynite (An66.0-71.0Or0.4), olivine (Fa43.6-47.3), Ti-chromite (Cr/(Cr+Al) = 0.72-0.79; 9.2-19.8 wt.% TiO2), chromite (Cr/(Cr+Al) = 0.71-0.86; 0.7-2.0 wt.% TiO2), merrillite, ilmenite, ulvöspinel and pyrrhotite. Olivine phenocrysts are zoned from Fa16.7 cores to Fa43.3 rims, and pyroxene phenocrysts have irregular cores of orthopyroxene (as magnesian as Fs17.9Wo2.4, with ~0.03 wt.% TiO2 and ~0.4 wt.% Al2O3) mantled by pigeonite (Fs25.4Wo4.4 to Fs37.0Wo12.7) with minor subcalcic augite (Fs21.7-24.0Wo30.8-31.1). Although textures and mineral compositions are similar to those in olivine-orthopyroxene-phyric shergottites NWA 1195 and NWA 2046 (Irving et al., 2004), none of these specimens seem to be terrestrially paired. Both olivine and pyroxene core compositions in NWA 2626 are less magnesian than those in NWA 2046, yet zoned to less ferroan rim and groundmass compositions (Irving et al., 2005), and NWA 1195 is a complete stone from a different, well-documented location near Safsaf, Morocco (Russell et al., 2002). Specimens: type specimen, 6.4 g, and one polished thin section, NAU; one polished thin section, UWS; main mass, Anonymous. Irving, A. J., Bunch, T. E., Kuehner, S. M. and Wittke, J. H. (2004) Petrology of primitive olivine-orthopyroxene-phyric shergottites NWA 2046 and NWA 1195: Analogies with terrestrial boninites and implications for partial melting of hydrous Martian m antle. Abstr. 35th Lunar Planet. Sci. Conf., #1444. Irving, A. J., Bunch, T. E., Wittke, J. H. and Kuehner, S. M. (2005) Olivine-orthopyroxene-phyric shergottites NWA 2626 and DaG 476: The Tharsis connection. Abstr. 36th Lunar Planet. Sci. Conf., #1229.
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